Journal of the American Chemical Society

THE ALIPHATIC DIOLEFINS. III. THE BEHAVIOR OF▵-1, 5-HEXADIENE AND▵-2, 4-HEXADIENE TOWARD HYDROCHLORIC ACID

F Cortese

Index: Cortese Journal of the American Chemical Society, 1930 , vol. 52, p. 1519

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Citation Number: 2

Abstract

I. Toward Concentrated Aqueous Acid.-Fifty cc. of hydrocarbon was shaken with 250 cc. of concentrated acid for twenty hours. The 50-cc. dark violet layer was washed with 10% sodium hydroxide, 15% sodium chloride, shaken with calcium chloride and dried over pearl ash. 13 g.: bp 21-25'at 6.5 mm.; colorless, mild rancid odor; turns yellow on standing. B. p. 122-126'at 760 mm.; d: 0, 9111; di6 0.8865; n': 1.4417; n': 1.4360. It titrated for one double ...