Journal of fluorine chemistry

Polyfluoro-compounds based on the cycloheptane ring system. Part 7. Ethoxypolyfluorocycloheptenes and polyfluorocycloheptenones

CM Jenkins, R Stephens, JC Tatlow

Index: Jenkins,C.; Stephens,R. Journal of Fluorine Chemistry, 1984 , vol. 25, p. 233

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Citation Number: 5

Abstract

Abstract Dodecafluorocycloheptene and ethanolic potassium hydroxide afforded 1- ethoxyundecafluorocycloheptene which at 410 C decomposed to decafluorocyclohept-2- enone. Decafluorohepta-l, 3-diene likewise gave mainly 1-ethoxynona-fluoro-, together with some 1, 4-diethoxyoctafluoro-cyclohepta-1, 3-diene. The 1-ethoxy-1, 3-diene was photoisomerised to 1-ethoxynonafluorobicyclo-(3, 2, 0) hept-6-ene (proving its structure), ...