New and improved methods for the radical decarboxylation of acids

DHR Barton, D Crich, WB Motherwell

Index: Barton, Derek H. R.; Crich, David; Motherwell, William B. Journal of the Chemical Society, Chemical Communications, 1983 , # 17 p. 939 - 941

Full Text: HTML

Citation Number: 131

Abstract

Carboxylic acid esters derived from-hydroxypyridine-2-thione undergo efficient radical chain decarboxylation to the corresponding nor-alkane on treatment with either tri-n-butylstannane or t-butylmercaptan; in the absence of these hydrogen atom donors a smooth decarboxylative rearrangement giving noralkyl 2-pyridy

Related Articles:

The invention of new radical chain reactions. Part VIII. Radical chemistry of thiohydroxamic esters; A new method for the generation of carbon radicals from carboxylic …

[Barton, Derek H. R.; Crich, David; Motherwell, William B. Tetrahedron, 1985 , vol. 41, # 19 p. 3901 - 3924]

Decarboxylative radical addition to vinylsulphones and vinylphosphonium bromide: Some further novel transformations of geminal (pyridine-2-thiyl) phenylsulphones.

[Barton; Boivin; Crepon nee da Silva; Sarma; Togo; Zard Tetrahedron, 1991 , vol. 47, # 34 p. 7091 - 7108]

The invention of new radical chain reactions. Part VIII. Radical chemistry of thiohydroxamic esters; A new method for the generation of carbon radicals from carboxylic …

[Barton, Derek H. R.; Crich, David; Motherwell, William B. Tetrahedron, 1985 , vol. 41, # 19 p. 3901 - 3924]

The invention of new radical chain reactions. Part VIII. Radical chemistry of thiohydroxamic esters; A new method for the generation of carbon radicals from carboxylic …

[Barton, Derek H. R.; Crich, David; Motherwell, William B. Tetrahedron, 1985 , vol. 41, # 19 p. 3901 - 3924]

Some further novel transformations of geminal (pyridine-2-thiyl) phenylsulphones

[Barton, Derek H. R.; Boivin, Jean; Sarma, Jadab; Silva, Elisabeth da; Zard, Samir Z. Tetrahedron Letters, 1989 , vol. 30, # 32 p. 4237 - 4240]

More Articles...