Advanced Synthesis & Catalysis

Efficient Synthesis of Dibenzoxaborininols from Diaryl Ethers and Their Application to Dibenzofuran Synthesis

L Niu, H Yang, Y Jiang, H Fu

Index: Niu, Liting; Yang, Haijun; Jiang, Yuyang; Fu, Hua Advanced Synthesis and Catalysis, 2013 , vol. 355, # 18 p. 3625 - 3632

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Citation Number: 8

Abstract

Abstract: A convenient and efficient method for the borylation of diaryl ethers leading to dibenzoxaborininols and the synthesis of dibenzofuran derivatives has been developed. The borylation involves the sequential three-step process: lithiation, borylation and hydrolysis. The synthesized dibenzoxaborininols could be readily transformed into dibenzofuran derivatives in good to excellent yields under palladium catalysis in the ...

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