Acyclic stereoselection. 36. Simple diastereoselection in the Lewis acid mediated reactions of enol silanes with aldehydes

CH Heathcock, SK Davidsen, KT Hug…

Index: Heathcock, Clayton H.; Davidsen, Steven K.; Hug, Kathleen T.; Flippin, Lee A. Journal of Organic Chemistry, 1986 , vol. 51, # 15 p. 3027 - 3037

Full Text: HTML

Citation Number: 183

Abstract

(THF), followed by reaction of the resulting lithium enolate with tert-butyldimethylsilyl chloride. The corresponding E ketene acetal 2 (89% isomeric purity) was prepared by the method of Ireland. 23 Initial attempts to prepare the trimethylsilyl ketene acetals derived ...