Synthesis of Verrucarin A and 3α??Hydroxyverrucarin A from Verrucarol and Diacetoxyscripenol (Anguidine). 39th Communication on Verrucarins and Roridins
P Mohr, M Tori, P Grossen, P Herold…
Index: Mohr; Tori; Grossen; et al. Helvetica Chimica Acta, 1982 , vol. 65, # 5 p. 1412 - 1417
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Citation Number: 41
Abstract
Summary The title compounds have been synthesized starting from verrucarol and diacetoxyscripenol (anguidine), (& 2)-muconic half ester and a derivative of ver- rucarinic acid. The latter has been prepared in optically active form from dimethyl 3-methylglu tarate. ... The verrucarins and roridins belong to an important and still growing class of macrocyclic di- and triesters produced by various strains of microorganisms3). Some metabolites are transformed by higher plants to yield ...
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