Fluorodienes. I. Synthesis from Cyclobutenes

JL Anderson, RE Putnam…

Index: Anderson,J.L. et al. Journal of the American Chemical Society, 1961 , vol. 83, p. 382 - 385

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Citation Number: 14

Abstract

Thermal scission of the allylic carbon-carbon bond of cyclobutenes to give 1, 3-dienes has been observed in a sufficient number of cases to suggest that it is a general reaction. A number of recently reported examples have been summarized by Vogel. 2 In contrast to the ease of cleavage noted in the hydrocarbon series, hexafluorocyclobutene is resistant to thermal isomerization. Thus, pyrolysis of hexafluoro~ yclobutene~ over active carbon at ...