Regioselective S-allylation of thiols with cyclic Baylis–Hillman acetates

I Erray, J Oble, G Poli, F Rezgui

Index: Erray, Imen; Oble, Julie; Poli, Giovanni; Rezgui, Farhat Journal of Sulfur Chemistry, 2014 , vol. 35, # 2 p. 128 - 136

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Citation Number: 4

Abstract

Therefore, a clean and economical S-allylation is still a very attractive goal for the construction of carbon–sulfur bonds, especially in functionalized allylic compounds such as Baylis–Hillman (BH) adducts. As it so happens, reactions of acyclic BH acetates with thiols,[2222. Kamimura A, Morita R, Matsuura K, Mitsudera H, Shirai M. A convenient stereoselective synthesis of β-lactams from β-hydroxy-α-thioalkylesters prepared from Michael/aldol tandem reaction or ...