Effet d'engrenage. VIII. Extension à des dérivés fonctionnels de l'alanine

…, C Roussel, J Metzger, J Sandström

Index: Blaive, Bruno; Roussel, Christian; Metzger, Jacques; Sandstroem, Jan Canadian Journal of Chemistry, 1980 , vol. 58, # 21 p. 2212 - 2220

Full Text: HTML

Citation Number: 8

Abstract

The gear effect has been discovered and studied for the first time on molecules where the interacting groups were alkyl substituents. In order to be closer to biochemical models, this effect has now been studied where one interacting group is asymmetric and functional. For this purpose eighteen new compounds derived from alanine have been prepared and studied by nmr and dynamic nmr. The gear effect is operating, and it appears to be a ...