Synthese de derives mono-ou disilicies au niveau d'un carbone fonctionnel

A Ekouya, R Calas, J Dunogues, C Biran…

Index: Ekouya,A. et al. Journal of Organometallic Chemistry, 1979 , vol. 177, p. 137 - 144

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Citation Number: 11

Abstract

Abstract Aliphatic saturated amides treated with Me 3 SiCl/Li/THF were found to react in two ways. Either alkoxysilanes, mono-or di-silylated at the functional carbon, or C-silylated amines were obtained dependent of the original amide structure and the experimental conditions.(Me 3 Si) 2 CHN (SiMe 3) 2 exhibited Physicochemical properties that are particular for hindered rotation about the C N bond. A general mechanism is proposed to ...