Distonic ions as reacting species

T Bjoernholm, S Hammerum…

Index: Bjoernholm, Thomas; Hammerum, Steen; Kuck, Dietmar Journal of the American Chemical Society, 1988 , vol. 110, # 12 p. 3862 - 3869

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Citation Number: 30

Abstract

Abstract: The characteristic reactions of a family of distonic radical cations show that the gas- phase chemistry of these species differs considerably from that of the isomeric conventional molecular ions. Fifteen distonic radical cations, derived from'CH2CHZNH3+ by introduction of alkyl substituents at C or N, have been demonstrated to be stable species whose reactions are characteristic of their structure. The predominant fragmentation and ...