Synthesis

Heck cross-coupling for synthesizing metal-complexing monomers

GE Southard, KA Van Houten, GM Murray

Index: Southard, Glen E.; Van Houten, Kelly A.; Murray, George M. Synthesis, 2006 , # 15 p. 2475 - 2477

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Citation Number: 6

Abstract

Abstract New polymerizable ligands for complexing metal ions have been synthesized. The polymerizable ligands were made by Heck cross-coupling of aromatic bromides with high pressure ethylene gas under mild conditions at room temperature. The vinyl substituted ligands were prepared in good yields and characterized by GC-MS, FT-NMR, FT-IR and microanalysis.

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