Synergistic effects in transition-metal complexes with two or three ligands
F Strobel, DP Ridge
Index: Strobel, F.; Ridge, D. P. Inorganic Chemistry, 1988 , vol. 27, p. 891 - 893
Full Text: HTML
Citation Number: 18
Abstract
The collision-induced decomposition spectra of several complexes ML, L2'and ML, L2L3', where M= Mn, Fe, and Co and L,= CO, NO, H20, and CH30H, are described. Treating branching ratios for ligand loss processes as equilibrium constants in these cases is justified empirically. Relative metal-ligand bond strengths derived from this treatment show antisymbiotic synergistic effects.
Related Articles:
[Sonnenfroh, D. M.; Farrar, J. M. Journal of the American Chemical Society, 1986 , vol. 108, # 12 p. 3521 - 3522]
[Le Caer; Heninger; Lemaire; Boissel; Maitre; Mestdagh Chemical Physics Letters, 2004 , vol. 385, # 3-4 p. 273 - 279]