Journal of Organometallic Chemistry

Dehydrofluorierung und spaltung der siliciumstickstoff-bindung in bortrifluorid/silylamin-systemen

G Elter, O Glemser, W Herzog

Index: Elter,G. et al. Journal of Organometallic Chemistry, 1972 , vol. 36, p. 257 - 265

Full Text: HTML

Citation Number: 17

Abstract

Zusammenfassung Boron trifluoride reacts at 0 with silylamines of the type Me 3 Si-NHR (R= Me, Et, Pr, i-Pr, Bu, t-Bu, Ph) to give adducts which are not stable at room temperature. Their decomposition proceeds with the elimination of Me 3 SiF and leads to the formation of aminoboranes having the general composition RNH-BF 2; these are unstable, too, and decompose further to give the corresponding primary amine/boron trifluoride adducts and ...