Dramatic acceleration of the catalytic process of the amination of allyl acetates in the presence of a tetraphosphine/palladium system
M Feuerstein, D Laurenti, H Doucet…
Index: Feuerstein; Laurenti; Doucet; Santelli Chemical Communications, 2001 , # 1 p. 43 - 44
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Citation Number: 31
Abstract
The cis, cis, cis-1, 2, 3, 4-tetrakis (diphenylphosphinomethyl)-cyclopentan e/[PdCl (C3H5)] 2 system catalyses allylic amination in good yields with a very high substrate/catalyst ratio; a turnover number of 680 000 and a turnover frequency of 8125 h− 1 can be obtained for the addition of dipropylamine to allyl acetate in the presence of this catalyst.
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