Gold (I)??Catalyzed Stereoselective Synthesis of Alkenyl Phosphates by Hydrophosphoryloxylation

P Nun, JD Egbert, MJ Oliva??Madrid…

Index: Nun, Pierrick; Egbert, Jonathan D.; Oliva-Madrid, Maria-Jose; Nolan, Steven P. Chemistry - A European Journal, 2012 , vol. 18, # 4 p. 1064 - 1067

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Citation Number: 11

Abstract

In recent decades, late-transition-metal-mediated crosscoupling reactions have become one of the most important tools to create CÀC bonds in organic synthesis.[1] Significant efforts have been devoted to developing catalytic systems, to expand the scope of useful substrates in these couplings. A significant goal is to develop systems that do not require aryl iodide or bromide, which represent the most common electrophilic moieties in Pd-catalyzed ...