1, 6-Anhydro-1-thio-β-D-glucopyranose (Thiolevoglucosan) and the Corresponding Sulfoxides and Sulfone

…, J Poláková, M Hamerníková, I Císařová…

Index: Budesinsky, Milos; Polakova, Jana; Hamernikova, Michaela; Cisarova, Ivana; Trnka, Tomas; Cerny, Miloslav Collection of Czechoslovak Chemical Communications, 2006 , vol. 71, # 3 p. 311 - 336

Full Text: HTML

Citation Number: 5

Abstract

Abstract Starting 1, 2, 3, 4-tetra-O-acetyl-6-O-tosyl-β-D-glucopyranose (3) was converted into 2, 3, 4-tri-O-acetyl-1-thio-6-O-tosyl-β-D-glucopyranose (6) via intermediate glycosyl bromide 4 and S-thiouronium salt 5. Treatment of compound 6 with sodium methoxide gave 1, 6- anhydro-1-thio-β-D-glucopyranose (thiolevoglucosan 2a). The isomeric sulfoxides 7 and 8 were prepared by selective oxidation of thiolevoglucosan 2a with hydrogen peroxide or 3- ...

Related Articles:

18F-Glyco-RGD peptides for PET imaging of integrin expression: efficient radiosynthesis by click chemistry and modulation of biodistribution by glycosylation

[Maschauer, Simone; Haubner, Roland; Kuwert, Torsten; Prante, Olaf Molecular Pharmaceutics, 2014 , vol. 11, # 2 p. 505 - 515]

Justus Liebig's Annalen Der Chemie. Über die Einwirkung des Ozons auf organische Verbindungen

[Helferich; Klein Justus Liebigs Annalen der Chemie, 1926 , vol. 450, p. 219,228 Justus Liebigs Annalen der Chemie, 1927 , vol. 455, p. 173,178]

Justus Liebig's Annalen Der Chemie. Über die Einwirkung des Ozons auf organische Verbindungen

[Helferich; Klein Justus Liebigs Annalen der Chemie, 1926 , vol. 450, p. 219,228 Justus Liebigs Annalen der Chemie, 1927 , vol. 455, p. 173,178]

Synthesis of sulfur-linked analogues of nigerose, laminarabiose, laminaratriose, gentiobiose, gentiotriose, and laminaran trisaccharide Y

[Contour-Galcera, Marie-Odile; Guillot, Jean-Michel; Ortiz-Mellet, Carmen; Pflieger-Carrara, Francoise; Defaye, Jacques; Gelas, Jacques Carbohydrate Research, 1996 , vol. 281, # 1 p. 99 - 118]

More Articles...