Silico-alkylation of Sodio Esters with Trimethyl-chlorosilane to Form Silyl Esters1

CR Hance, CR Hauser

Index: Hance; Hauser Journal of the American Chemical Society, 1953 , vol. 75, p. 994

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Citation Number: 17

Abstract

These reactions are assumed to produce the C-derivatives, I and 11, rather than the 0- derivative, for example, 111. The related reaction of sodioacetoacetic ester with triethylchlorosilane has been assumed to form such an 0-derivative (IV) 4 but this structure has been questioned. 6

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