Réactions non classiques au cours de l'alkylation de dérivés d'éléments de la colonne IVB par des réactifs de Grignard: III. Étude du comportement de dérivés RnSiΣ4 …

MB Lacout-Loustalet, JP Dupin, F Metras…

Index: Lacout-Loustalet,M.B. et al. Journal of Organometallic Chemistry, 1971 , vol. 31, p. 187 - 204

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Citation Number: 12

Abstract

Abstract The reduction of derivatives of the type R n Siσ 4-n (σ= Cl, OCH 3) by some organomagnesium compounds RMgX at high temperature (⩾ 80) leads to the hydrosilanes RR'SiH 2 and RR'2 SiH in various ratios according to the considered reagents. The results described in this publication constitute a first approach in the knowledge of the mechanism of these reductions. A deeper study of the mechanism is the subject of the following ...