The Journal of organic chemistry

Synthesis of Allylic and Propargylic Primary Amines by Reaction of Organometallic Reagents with α-Amidoalkyl Sulfones

T Mecozzi, M Petrini

Index: Mecozzi, Tiziana; Petrini, Marino Journal of Organic Chemistry, 1999 , vol. 64, # 24 p. 8970 - 8972

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Citation Number: 109

Abstract

Allylic and propargylic amines play a prominent role in organic synthesis, and their importance continues to grow with time. 1 A plethora of synthetic methods have been devised for the preparation of allylic amines, including substitution reactions with nucleophilic nitrogen, 2 use of azallylic anions, 3 coupling reactions, 4 and palladiumcatalyzed reactions. 5 Similar approaches can also be used for the synthesis of ...