Copper-TBAF catalyzed arylation of amines and amides with aryl trimethoxysilane
…, M Liu, Z Ye, J Ding, H Wu, J Cheng
Index: Lin, Baoda; Liu, Miaochang; Ye, Zhishi; Ding, Jinchang; Wu, Huayue; Cheng, Jiang Organic and Biomolecular Chemistry, 2009 , vol. 7, # 5 p. 869 - 873
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Citation Number: 23
Abstract
A copper-catalyzed C–N bond forming reaction among aryl siloxane and primary, secondary amines as well as amides has been described. The reaction was conducted in the presence of P (C6F5) 3 and 4 Å molecular sieves in CH2Cl2 at room temperature under O2. A catalytic amount of TBAF was employed to activate aryl siloxanes.
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