Chemistry Letters

Synthesis of Azaspirodienones via Intramolecular Cyclization of p-Hydroxybenzylacetone Oximes and Their Transformation into Quinolines.

H Kusama, K Uchiyama, Y Yamashita, K Narasaka

Index: Kusama, Hiroyuki; Uchiyama, Katsuya; Yamashita, Yuko; Narasaka, Koichi Chemistry Letters, 1995 , # 8 p. 715 - 716

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Citation Number: 28

Abstract

抄録 Intramolecular cyclization reaction on the nitrogen atom of oximes of< I> p- hydroxybenzylacetone derivatives proceeds by the treatment with tetrabutylammonium perrhenate and trifluoromethanesulfonic acid in refluxing 1, 2-dichloroethane to afford azaspirodienones in good yield. The azaspirodienones are transformed into quinolines< I> via dienone-phenol rearrangement.

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