The synthesis of tricarbonyl (2, 4-cycloheptadiene-1, 6-dione) iron and tricarbonyl (2, 4-cyclooctadiene-1, 6-dione) iron
N Morita, S Ito, T Asao
Index: Morita, Noboru; Ito, Shunji; Asao, Toyonobu Journal of Organometallic Chemistry, 1993 , vol. 460, # 1 p. 67 - 72
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Abstract
Abstract Tricarbonyl (6-hydroxy-2, 4-cycloheptadien-1-one) iron derived from tricarbonyl (tropone) iron was easily oxidized to give tricarbonyl (2, 4-cycloheptadiene-1, 6-dione) iron. This procedure was also extended to tricarbonyl (2-substituted tropone) iron and exo (bicyclo [5.1. O] octa-3, 5-dien-2-one) tricarbonyliron to yield tricarbonyl (2-substituted 2, 4- cycloheptadiene-1, 6-dione) iron and tricarbonyl (2, 4-cyclooctadiene-1, 6-dione) iron, ...
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