Proton magnetic resonance of some 9, 10-dihydroanthracenes

W Carruthers, GE Hall

Index: Carruthers,W.; Hall,G.E. Journal of the Chemical Society [Section] B: Physical Organic, 1966 , p. 861 - 864

Full Text: HTML

Citation Number: 3

Abstract

Reaction of dilithio-or disodio-anthracene with t-butyl chloride affords a mixture of 9-t-butyl- and 9, 10-di-t-butyl-9, 10-dihydroanthracene with some 1, 4-di-t-butyl-1, 4- dihydroanthracene. The nuclear magnetic resonance (nmr) spectrum of the 9, 10-di-t-butyl compound shows that it has either a planar conformation of the central ring or the trans configuration with rapid interconversion of the two conformers. Homo-allylic coupling is ...

Related Articles:

The metal-ammonia reduction of mono-and dinaphthylbenzenes

[Marcinow, Zbigniew; Rabideau, Peter W. Journal of Organic Chemistry, 1990 , vol. 55, # 12 p. 3812 - 3816]

Photochemistry of 1-phenyl-1, 2-dihydronaphthalene in methanol

[Woning, Jan; Lijten, Frank A. T.; Laarhoven, Wim H. Journal of Organic Chemistry, 1991 , vol. 56, # 7 p. 2427 - 2435]

The photochemical rearrangement of 1, 2??dihydronaphthalenes into 1, 4??dihydronaphthalenes induced by amines

[Cuppen, Th. J. H. M.; Berendsen, N.; Laarhoven, W. H. Recueil des Travaux Chimiques des Pays-Bas, 1990 , vol. 109, # 3 p. 168 - 171]

The metal-ammonia reduction of mono-and dinaphthylbenzenes

[Marcinow, Zbigniew; Rabideau, Peter W. Journal of Organic Chemistry, 1990 , vol. 55, # 12 p. 3812 - 3816]

The photochemical rearrangement of 1, 2??dihydronaphthalenes into 1, 4??dihydronaphthalenes induced by amines

[Cuppen, Th. J. H. M.; Berendsen, N.; Laarhoven, W. H. Recueil des Travaux Chimiques des Pays-Bas, 1990 , vol. 109, # 3 p. 168 - 171]

More Articles...