Kinetics and products of propargyl (C3H3) radical self??reactions and propargyl??methyl cross??combination reactions

A Fahr, A Nayak

Index: Fahr, Askar; Nayak, Akshaya International Journal of Chemical Kinetics, 2000 , vol. 32, # 2 p. 118 - 124

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Citation Number: 45

Abstract

Abstract Propargyl (HC [TRIPLE BOND] C [BOND] CH 2) and methyl radicals were produced through the 193-nm excimer laser photolysis of mixtures of C 3 H 3 Cl/He and CH 3 N 2 CH 3/He, respectively. Gas chromatographic and mass spectrometric (GC/MS) product analyses were employed to characterize and quantify the major reaction products. The rate constants for propargyl radical self-reactions and propargyl-methyl cross-combination reactions ...