Synthetic communications

New synthetic method of p-nitrocalixarenes

WC Zhang, YS Zheng, ZT Huang

Index: Zhang, Wen-Chun; Zheng, Yan-Song; Huang, Zhi-Tang Synthetic Communications, 1997 , vol. 27, # 21 p. 3763 - 3767

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Citation Number: 26

Abstract

Wen-Chun Zhang, Yan-Song Zheng and %-Tang Huang* ... Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100080, China. ... Abstract: Calixarenes 1 were directly nitrated with potassium nitrate and aluminum chloride to give p-nitrocalixarenes 2 in good yields. Formation of p-nitrocalix[4]arene (2a) fiom reaction of p-bromomethylcalix[4]arene (3) with siier nitrate is also described. ... Calixarenes are cavity-containing macrocyclic compounds which are ...

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