Hg (OTf) 2–BINAPHANE??Catalyzed Enantioselective Anilino Sulfonamide Allyl Alcohol Cyclization

…, K Namba, H Imagawa, M Nishizawa

Index: Yamamoto, Hirofumi; Ho, Elisabeth; Namba, Kosuke; Imagawa, Hiroshi; Nishizawa, Mugio Chemistry - A European Journal, 2010 , vol. 16, # 37 p. 11271 - 11274

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Citation Number: 39

Abstract

Direct allylic amination of allylic alcohols with amine nucleophiles to produce water as the only byproduct is one of the most attractive reactions in modern organic synthesis.[1] Therefore, significant resources have been devoted to developing the latent ability of transition-metal reagents with the aim of achieving allylic amination from allylic alcohols in high catalytic turnover.[2, 3] Recently, Shibasaki, Matsunaga, and co-workers reported the ...