Journal of Fluorine Chemistry

The interaction of polyfluoroaromatic compounds with oxygen containing radicals

AA Bogachev, LS Kobrina, GG Yakobson

Index: Bogachev, A. A.; Kobrina, L. S.; Yakobson, G. G. Journal of Fluorine Chemistry, 1985 , vol. 29, p. 143

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Abstract

Abstract Addition of oxygen containing radicals (HO·, t-BuO·, C 6 F 5 COO·, C 6 F 5 SO· 2) to octafluoronaphthalene occurs mainly in the 1-position. The radical intermediates are stabilised by formation of heptafluoronaphthoxyl radical, further transformations of which lead mainly to polyfluorinated derivatives of 1-oxodihydronaphthalenes and 1, 4- naphthoquinone. Reactions with HO· may involve aromatic ring cleavage both in ...

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