Tetrahedron letters

General synthesis of 2-alkyn-1-ylboronates in excellent isomeric purity

R Soundararajan, G Li, HC Brown

Index: Soundararajan, Raman; Li, Guisheng; Brown, Herbert C. Tetrahedron Letters, 1994 , vol. 35, # 48 p. 8961 - 8964

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Citation Number: 12

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... 2-Alkyn-1-ylboronates have been synthesized successfully, in excellent isomeric purity, via the in situ homologation of alkyn-1-ylboronates with LiCH 2 I. The relative reactivities exhibited by various LiCH 2 X reagents (X=Cl; Br; I) are described. ... 2-Alkyn-1-ylboronates have ...

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