Reactions of NH radicals. III. Photolysis of HN3 in the presence of C2H4 at 313nm.
S Kodama
Index: Kodama, Sukeya Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 8 p. 2363 - 2370
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Citation Number: 13
Abstract
Photolysis of HN 3 vapor in the presence of C 2 H 4 was studied at 313 nm and 30° C. The main products were N 2, H 2, CH 4, C 2 H 6, NH 4 N 3, C 2 H 5 N· HN 3 (salt of C 2 H 5 N (azomethines) with HN 3), HCN, CH 3 CN, CH 3 N 3, and C 2 H 5 N 3. The quantum yields of these products were measured as a function of the light intensity and pressures of HN 3 and C 2 H 4. The following mechanism for the main reactions was infered: HN 3+ hν (313 ...
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