One-pot reduction of aryl iodides using 4-dmap methiodide salt
J Garnier, JA Murphy, SZ Zhou, AT Turner
Index: Garnier, Jean; Murphy, John A.; Zhou, Sheng-Ze; Turner, Andrew T. Synlett, 2008 , # 14 p. 2127 - 2131
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Citation Number: 9
Abstract
Abstract An efficient one-pot procedure is described for the reduction of aryl iodides to aryl anions using a structurally simple bis-pyridinylidene electron donor, prepared in situ by treating 4-DMAP methiodide salt with base. The results show (i) that pyridinylidene carbenes can be easily used for intermolecular CC bond formation,(ii) that bis-pyridinylidenes demonstrate superior robustness compared to electron-donor systems based on bis- ...
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