Trinuclear Copper (I)??bipyridine Triskelion: Template/Bascule Control of Coordination Complex Stereochemistry in a Trefoil Knot Precursor
…, M Benaglia, S Toyota, K Hardcastle…
Index: Woods, Craig R.; Benaglia, Maurizio; Toyota, Shinji; Hardcastle, Kenneth; Siegel, Jay S. Angewandte Chemie - International Edition, 2001 , vol. 40, # 4 p. 749 - 751
Full Text: HTML
Citation Number: 51
Abstract
Abstract The construction of molecules such as knots and links can be facilitated by using metal–ligand coordination complexes as template structures; however, the control of the stereochemistry by cooperative steric interactions among metal–ligand sites remains a challenge. A simple, but general, cantilever control mechanism is demonstrated here through the stereoselective synthesis of a trinuclear copper (I)-bipyridine triskelion (see ...
Related Articles:
[Bouillon, Alexandre; Lancelot, Jean-Charles; Santos, Jana Sopkova De Oliveira; Collot, Valerie; Bovy, Philipppe R.; Rault, Sylvain Tetrahedron, 2003 , vol. 59, # 50 p. 10043 - 10049]
Synthesis of Oligopyridines and Their Metal Complexes as Precursors to Topological Stereoisomers
[Benaglia, Maurizio; Ponzini, Francesco; Woods, Craig R.; Siegel, Jay S. Organic Letters, 2001 , vol. 3, # 7 p. 967 - 969]
[Bouillon, Alexandre; Lancelot, Jean-Charles; Santos, Jana Sopkova De Oliveira; Collot, Valerie; Bovy, Philipppe R.; Rault, Sylvain Tetrahedron, 2003 , vol. 59, # 50 p. 10043 - 10049]
[Bouillon, Alexandre; Lancelot, Jean-Charles; Santos, Jana Sopkova De Oliveira; Collot, Valerie; Bovy, Philipppe R.; Rault, Sylvain Tetrahedron, 2003 , vol. 59, # 50 p. 10043 - 10049]
[Bouillon, Alexandre; Lancelot, Jean-Charles; Santos, Jana Sopkova De Oliveira; Collot, Valerie; Bovy, Philipppe R.; Rault, Sylvain Tetrahedron, 2003 , vol. 59, # 50 p. 10043 - 10049]