Manganese??Catalyzed and Promoted Reactions of H??Phosphinate Esters

…, O Berger, F Gelat, JL Montchamp

Index: Fisher, Henry C.; Berger, Olivier; Gelat, Fabien; Montchamp, Jean-Luc Advanced Synthesis and Catalysis, 2014 , vol. 356, # 6 p. 1199 - 1204

Full Text: HTML

Citation Number: 27

Abstract

Abstract: H-Phosphinates react with alkenes and alkynes using catalytic manganese (II) acetate. Under stoichiometric conditions with manganeseACHTUNGTRENNUNG (III) acetate or with catalytic manganese (II) acetate+ excess manganese (II) oxide various reactions like arylation or cyclization through radical oxidative arylation can take place. Whereas the chemistry of manganese is already well developed for the functionalization ...