A New Synthetic Method for an Indolizidine Skeleton by CN Bond Formation via a. PI.-Allylpalladium Complex

Y Yamada, W Takahashi, Y Asada, J Holiuchi…

Index: Yamada, Yaeko; Takahashi, Wakako; Asada, Yoshihisa; Holiuchi, Junko; Takeda, Kazuyoshi; Harigaya, Yoshihiro Chemical and Pharmaceutical Bulletin, 2004 , vol. 52, # 9 p. 1082 - 1085

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Abstract

Pd (0)-catalyzed intramolecular cyclic reaction via a π-allylpalladium complex provided an indolizidine skeleton in satisfactory high and reproducible yields by using allylic compound having an acetoxyl group as a leaving group. These results must be available for syntheses of various functional indolizidine alkaloids.