Tetrahedron Letters

On the gif oxidation of alicyclic tertiary amines

DHR Barton, J Boivin, D Gaudin, K Jankowski

Index: Barton, D.H.R; Boivin, J.; Gaudin D.; Jankowski, K. Tetrahedron Letters, 1989 , vol. 30, # 11 p. 1381 - 1382

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Citation Number: 9

Abstract

Abstract Oxidation of various tertiary amines by the Gif IV system based on an iron catalyst associated with a reductant (zinc) and molecular oxygen, led to a mixture of the ketoderivatives and the corresponding lactams. Steric hindrance and electron withdrawing substituents exert a deactivating effect on the oxidation.

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