Reactions of 1-aryl-2-bromodiazene 1-oxides with acids and bases

AY Tyurin, AM Churakov, SL Ioffe, YA Strelenko…

Index: Tyurin; Churakov; Ioffe; Strelenko; Tartakovsky Russian Chemical Bulletin, 1997 , vol. 46, # 3 p. 592 - 594

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Abstract

Abstract The reactions of 1-aryl-2-bromodiazene 1-oxides with HCl in nonaqueous media give aryldiazonium chlorides, while 1, 3, 3-substituted triazenes-1 are formed in the reactions with secondary amines. Using 2-{15 N} label, it was shown that the aryl group does not migrate in these reactions.