The acid-catalysed decomposition of some β-azido-carbonyl compounds
AJ Davies, ASR Donald, RE Marks
Index: Davies,A.J. et al. Journal of the Chemical Society [Section] C: Organic, 1967 , p. 2109 - 2112
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Citation Number: 22
Abstract
The Schmidt reaction of acraldehyde, methyl vinyl ketone, and ethyl vinyl ketone leads to the formation of ammonia with pyruvaldehyde, biacetyl, and pentane-2, 3-dione, respectively, through the intermediate formation of β-azidocarbonyl compounds. For methyl isopropenyl ketone and mesityl oxide neither the Schmidt reaction of the ketone nor the acid-catalysed decomposition of the β-azido-ketone leads to similar products.
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