Advanced synthesis & catalysis

Hydrogen/Deuterium Exchange Reactions of Olefins with Deuterium Oxide Mediated by the Carbonylchlorohydrido??tris (triphenylphosphine) ruthenium (II) Complex

SKS Tse, P Xue, Z Lin, G Jia

Index: Tse, Sunny Kai San; Xue, Peng; Lin, Zhenyang; Jia, Guochen Advanced Synthesis and Catalysis, 2010 , vol. 352, # 9 p. 1512 - 1522

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Citation Number: 25

Abstract

Abstract The catalytic properties of several ruthenium, osmium and rhodium hydride complexes for hydrogen/deuterium (H/D) exchange between olefins and deuterium oxide (D 2 O) were investigated. The most effective catalytic precursor was found to be the carbonylchlorohydridotris (triphenylphosphine) ruthenium (II) complex. Through H/D exchange between metal hydride and D 2 O, and reversible olefin insertion into an Ru [ ...