Simple enols. 4. Generation of some new simple enols in solution and the kinetics and mechanism of their ketonization

B Capon, AK Siddhanta, C Zucco

Index: Capon, Brian; Siddhanta, Arup K.; Zucco, Cesar Journal of Organic Chemistry, 1985 , vol. 50, # 19 p. 3580 - 3584

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Citation Number: 29

Abstract

The simple enols [O-2H]-2-hydroxypropene,[0-2H]-3-chloro-2-hydroxypropene, 2, 2- dichlorovinyl alcohol, and hydroxypropadiene have been generated from reactive precursors in solution and characterized by NMR spectroscopy. The kinetics of ketonization of 3-chloro-2-hydroxypropene, hydroxypropadiene, and of the previously described (2)-prop- 1-en-1-01 and 2-methylprop-1-en-1-01 were studied by UV spectrophotometry at 15" C. It ...