Energy barrier for 1, 2-hydrogen migration in benzylchlorocarbene

MTH Liu

Index: Liu, Michael T. H. Journal of the Chemical Society, Chemical Communications, 1985 , # 14 p. 982 - 984

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Citation Number: 18

Abstract

The intermolecular-intramolecular rate constants derived from the thermolysis and photolysis of 3-chloro-3-benzyldiazirine in tetramethylethylene gave an excellent Arrhenius plot; an activation energy of 6.4 kcal mol–1 (26.8 kJ mol–1) was obtained for the 1, 2-H migration in benzylchlorocarbene.

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