Journal of the American Chemical Society

Preparation of 1-C14-Propene-1 and the Mechanism of Permanganate Oxidation of Propene1

BA Fries, M Calvin

Index: Fries; Calvin Journal of the American Chemical Society, 1948 , vol. 70, p. 2237,2238

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Citation Number: 14

Abstract

Summary The chain peroxide mechanism of autoxidation is briefly compared with the semiquinone mechanism. It is pointed out that the coenzymes involved in biological oxidation-reductions are much more likely to undergo reaction with oxygen via the semiquinone mechanism than by the chain, bound peroxide mechanism.