Australian Journal of Chemistry

Radical reactions of p-nitrobenzylidene halides with aci-nitronate ions

DJ Freeman, RK Norris, SK Woolfenden

Index: Freeman,D.J. et al. Australian Journal of Chemistry, 1978 , vol. 31, p. 2477 - 2490

Full Text: HTML

Citation Number: 7

Abstract

Abstract The radical S RN 1 and subsequent E RC 1 reactions of p-nitrobenzylidene dibromide (2b) and bromide chloride (2c) with the lithium salt (1a) and the tetrabutylammonium salt (1b)(under phase-transfer conditions) of 2-nitropropane are discussed and compared with the reactions of the dichloride (2a). The S RN 1 and E RC 1 sequence occurs in rapid succession in the reaction of (2b), in contrast to the reactions of ( ...

Related Articles:

Interesting products derived from the reactions of 2, 3-diamino-2, 3-dimethylbutane

[Gagnon, Janet L.; Walters, Thomas R.; Zajac, Walter W.; Buzby, John H. Journal of Organic Chemistry, 1993 , vol. 58, # 24 p. 6712 - 6715]

Sur la reactivite de gem-bromonitroalcanes en presence de thiolates.

[Amrollah-Madjdabadi, Ali; Beugelmans, Rene; Lechevallier, Andre Tetrahedron Letters, 1987 , vol. 28, # 39 p. 4525 - 4528]

Ion pairing and solvent effects in the reactivity of anions towards free radicals

[Russell, Glen A.; Ros, Francisco; Mudryk, Boguslaw Journal of the American Chemical Society, 1980 , vol. 102, # 25 p. 7601 - 7603]

The mechanism of catalyst deactivation and by-product formation in acetone ammoximation catalyzed by hollow titanium silicalite

[Wang, Yi; Zhang, Shengjian; Zhao, Yingxian; Lin, Min Journal of Molecular Catalysis A: Chemical, 2014 , vol. 385, p. 1 - 6]

Nucleic Acid Related Compounds. 105. Synthesis of 2', 3'-Didehydro-2', 3'-dideoxynucleosides from Ribonucleoside Cyclic 2', 3'-(Sulfates or Phosphates) or 2', 3'- …

[Park, Kwanghee Koh; Lee, Chul Woo; Choi, Sook Young Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1992 , # 5 p. 601 - 604]

More Articles...