Catalyst??Free Dehydrative α??Alkylation of Ketones with Alcohols: Green and Selective Autocatalyzed Synthesis of Alcohols and Ketones
…, J Chen, H Tian, X Yuan, S Li, C Zhou…
Index: Xu, Qing; Chen, Jianhui; Tian, Haiwen; Yuan, Xueqin; Li, Shuangyan; Zhou, Chongkuan; Liu, Jianping Angewandte Chemie - International Edition, 2014 , vol. 53, # 1 p. 225 - 229 Angew. Chem., 2014 , vol. 126, # 1 p. 229 - 233,5
Full Text: HTML
Citation Number: 36
Abstract
Abstract Direct dehydrative α-alkylation reactions of ketones with alcohols are now realized under simple, practical, and green conditions without using external catalysts. These catalyst- free autocatalyzed alkylation methods can efficiently afford useful alkylated ketone or alcohol products in a one-pot manner and on a large scale by C [DOUBLE BOND] C bond formation of the in situ generated intermediates with subsequent controllable and ...
Related Articles:
[Xu, Qing; Chen, Jianhui; Liu, Quan Advanced Synthesis and Catalysis, 2013 , vol. 355, # 4 p. 697 - 704]
Ruthenium-catalyzed regioselective α-alkylation of ketones with primary alcohols
[Cho, Chan Sik; Kim, Bok Tae; Kim, Tae-Jeong; Chul Shim, Sang Tetrahedron Letters, 2002 , vol. 43, # 44 p. 7987 - 7989]
[Jiang, Quanbin; Guo, Tenglong; Wang, Qingfu; Wu, Ping; Yu, Zhengkun Advanced Synthesis and Catalysis, 2013 , vol. 355, # 9 p. 1874 - 1880]
[Calo, Vincenzo; Nacci, Angelo; Lopez, Luigi; Napola, Annalisa Tetrahedron Letters, 2001 , vol. 42, # 28 p. 4701 - 4703]