Chemistry–A European Journal

The Versatile, Efficient, and Stereoselective Self??Assembly of Transition??Metal Helicates by Using Hydrogen??Bonds

SG Telfer, R Kuroda

Index: Telfer, Shane G.; Kuroda, Reiko Chemistry - A European Journal, 2005 , vol. 11, # 1 p. 57 - 68

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Citation Number: 58

Abstract

Abstract A diverse range of dinuclear double-stranded helicates in which the ligand strand is built up by using hydrogen-bonding has been synthesized. The helicates, formulated as [Co 2 (L) 2 (LH) 2 X 2], readily self-assemble from a mixture of a suitable pyridine–alcohol compound (L; for example, 6-methylpyridine-2-methanol, 1), and a CoX 2 salt in the presence of base. Nine such helicates have been characterized by X-ray crystallography. ...

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