Kinetics and hydrolysis mechanism of triasulfuron

I Braschi, L Calamai, MA Cremonini…

Index: Braschi, Ilaria; Calamai, Luca; Cremonini, Mauro Andrea; Fusi, Paolo; Gessa, Carlo; Pantani, Ottorino; Pusino, Alba Journal of Agricultural and Food Chemistry, 1997 , vol. 45, # 11 p. 4495 - 4499

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Citation Number: 51

Abstract

The hydrolysis of the sulfonylurea herbicide triasulfuron [(2-(2-chloroethoxy)-N-[[4-methoxy- 6-methyl-1, 3, 5-triazin-2-yl) amino] carbonyl] benzenesulfonamide] was studied in aqueous buffers of pH values 2, 3, 4, 5, 6, 7, and 9. The reaction was of first-order and pH-dependent. Triasulfuron was more persistent in neutral or weakly basic than in acidic solution. Five metabolites have been isolated and identified. At all pH values studied, the primary ...