Reaction of diazonium salts with transition metals: IX. Reaction of vinyltrimethylsilane with arenediazonium tetrafluoroborates under palladium (0) catalysis

K Kikukawa, K Ikenaga, K Kono, K Toritani…

Index: Kikukawa, Kiyoshi; Ikenaga, Kazutoshi; Kono, Kiyoshi; Toritani, Koji; Wada, Fumio; Matsuda, Tsutomu Journal of Organometallic Chemistry, 1984 , vol. 270, # 3 p. 277 - 282

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Citation Number: 39

Abstract

Abstract Arenediazonium tetrafluoroborates (ArN 2 BF 4 where Ar Ph, 4-MeC 6 H 4, 4-BrC 6 H 4, 4-IC 6 H 4 and 4-NO 2 C 6 H 4) reacted easily with CH 2 CHSiMe 3 at 25 δC to give ArCH CH 2,(E-ArCH CHSiMe 3 and Ar (Me 3 Si) C CH 2 in excellent yields under palladium (O) catalysis.(E)-ArCH CHSiMe 3 compounds were obtained predominantly and isolated in good yields by using an excess of CH 2 CHSiMe 3 over ArN 2 BF 4. ...