Catalytic adaptive recognition of thiol (SH) and selenol (SeH) groups toward synthesis of functionalized vinyl monomers
…, VN Khrustalev, K Morokuma, DG Musaev
Index: Ananikov, Valentine P.; Orlov, Nikolay V.; Zalesskiy, Sergey S.; Beletskaya, Irina P.; Khrustalev, Victor N.; Morokuma, Keiji; Musaev, Djamaladdin G. Journal of the American Chemical Society, 2012 , vol. 134, # 15 p. 6637 - 6649
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Citation Number: 45
Abstract
An unprecedented sustainable procedure was developed to produce functionalized vinyl monomers H2C C (R)(FG) starting from a mixture of sulfur and selenium compounds as a functional group donor (FG= S or Se). The reaction serves as a model for efficient utilization of natural resources of sulfur feedstock in oil and technological sources of sulfur/selenium. The catalytic system is reported with amazing ability to recognize SH/SeH groups in the ...
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