Selective sp3 C–H Bond Activation Based on a Carbocation Relay: Friedel–Crafts Reaction with Alkanes as the Alkylating Component
J Wang, P Zhou, Y Wang
Index: Wang, Jie; Zhou, Pengfei; Wang, Yang European Journal of Organic Chemistry, 2011 , # 2 p. 264 - 270
Full Text: HTML
Citation Number: 2
Abstract
Abstract A highly efficient and selective intramolecular Friedel–Crafts reaction of 3- methylbutyl or 4-methylpentyl-substituted aromatics has been developed using a carbocation relay strategy through selective sp 3 C–H bond activation, providing a facile and cost-effective approach for the construction of benzocyclic compounds. A variety of 1, 1- dimethylindane and naphthalene derivatives have been prepared from very simple ...
Related Articles:
Regioselective cyclopentane ring formation mediated by titanocene chloride
[Rigollier, Pascal; Young, Jonathan R.; Fowley, Lissa A.; Stille, John R. Journal of the American Chemical Society, 1990 , vol. 112, # 25 p. 9441 - 9442]
A convenient preparation of xanthene dyes
[Fillion, Eric; Carson, Rebekah J.; Trepanier, Vincent E.; Goll, Julie M.; Remorova, Anna A. Journal of the American Chemical Society, 2004 , vol. 126, # 47 p. 15354 - 15355]
Reactions of benzyl carbinols with fluorosulfuric acid
[Barrow, Colin J.; Bright, Steven T.; Coxon, James M.; Steel, Peter J. Journal of Organic Chemistry, 1989 , vol. 54, # 11 p. 2542 - 2549]
[Warrick,P.; Saunders,W.H. Journal of the American Chemical Society, 1962 , vol. 84, p. 4095 - 4100]
The Potassium-catalyzed Reaction of Olefins with Arylalkanes1
[Schaap; Pines Journal of the American Chemical Society, 1957 , vol. 79, p. 4967,4968]