… Ethyl N-benzoyldithiocarbamate: two independent hydrogen-bonded R_ {\ bf 2}^{\ bf 2}(8) dimers of different symmetry linked into chains by a C—H⋯ π (arene …

…, J Cobo, H Insuasty, M Estrada, E Cortes…

Index: Low, John N.; Cobo, Justo; Insuasty, Henry; Estrada, Martin; Cortes, Edward; Glidewell, Christopher Acta Crystallographica Section C: Crystal Structure Communications, 2004 , vol. 60, # 7 p. o483-o485

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Citation Number: 2

Abstract

The title compound, C10H11NOS2, crystallizes with Z′= 2 in space group C2/c. The molecules are linked by two N—H⋯ S hydrogen bonds [H⋯ S= 2.60 and 2.62 Å, N⋯ S= 3.350 (2) and 3.490 (2) Å, and N—H⋯ S= 143 and 172°] into two distinct types of R_2^ 2 (8) dimer, viz. one generated by inversion and the other by a twofold rotation axis. A single C— H⋯ π (arene) hydrogen bond links the two types of dimer into chains.