Preparation d'alcools acetyleniques et propargyliques F-alkyles

P Moreau, N Naji, A Commeyras

Index: Moreau, Patrice; Naji, Naima; Commeyras, Auguste Journal of Fluorine Chemistry, 1985 , vol. 30, p. 315 - 328

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Citation Number: 6

Abstract

A number of α-β acetylenic carbinols R F CCC(OH)RR′, in which the acetylenic proton was substituted by a F-alkyl group, were first prepared, from a classical reaction of (F-alkynyl)- lithium derivatives R F CCLi upon various carbonyl compounds. ... On another hand, the reaction of propargyl bromide metallic complexes (organoaluminic, or ultrasonic irradiation activated organozinc) upon some polyfluorinated ketones R F COR led to the formation, ...